The answer must be no, otherwise the identity would be a H.S. operator. However, whats wrong with the following:
We have by Schwartz kernel theorem
$k_I( \phi\otimes\psi)=(I\phi,\psi)_{L^2}$
Therefore, for $\psi,\phi \in D(x)$ we have
$|k_I( \phi\otimes\psi)|=|(I\phi,\psi)_{L^2}|\le ||\phi||_{L^2}||\psi||_{L^2}=||\phi\otimes\psi||_{L^2\otimes L^2}$
Since $D(X)\otimes D(X)$ is dense in $L^2(X)\otimes L^2(X)$ and $L^2(X)\otimes L^2(X)\cong L^2({X^2})$ the above lines seems to show that $k_I$ is in $(L^2({X^2}))^*=L^2({X^2})$.