Let's put it formally...
Let $n$ be a positive integer and $E = \{-1,+1\}^n$. Consider the set $\mathcal{P}$ of all the probability measures $\mu$ on $E$ such that $$ \mu ( \pi_i^{-1} \{-1\} ) = \mu ( \pi_i^{-1} \{+1\} ) = \frac12 $$ where $\pi_i : E \rightarrow \{-1,+1\}$ is the canonical projection onto the $i^\text{th}$ component of $E$, i.e. $\pi_i(x_1, \dots, x_n) = x_i$.
How can I parametrize $\mathcal{P}$?
Also, letting $\mathcal{C}$ be the set of all $n \times n$ correlation matrices, consider the map $c: \mathcal{P} \rightarrow \mathcal{C} $ that assigns to each probability measure in $\mathcal{P}$ its correlation matrix. Is $c$ injective? Surjective?
For the simple case $n=2$, it is clear to me that we can put $\mathcal{P}$ in a bijection with $[0,\frac12]$. For $a \in [0,\frac12]$, define $\mu$ as $$ \mu \{-1,-1\} = \mu \{+1,+1\} = a \\ \mu \{-1,+1\} = \mu \{+1,-1\} = \frac12 - a $$ It's also clear that $c$ is bijective since the correlation is $4a-1$.
But what about the case of arbitrary $n$?