Let me use $n=5$ to show the result. It is easy to generalize the result for general $n$. For $n=5$, let $a_k=\tan\frac{k\pi}{11}$ and
$$ A=\left(\begin{matrix}a_1&0&0&0&0\\
0&-a_2&0&0&0\\
0&0&a_3&0&0\\
0&0&0&-a_4&0\\
0&0&0&0&a_5\\
\end{matrix}\right),D=\left(\begin{matrix}0&1&0&0&0\\
1&0&1&0&0\\
0&1&0&1&0\\
0&0&1&0&1\\
0&0&0&1&1\\
\end{matrix}\right). $$
Then the corresponding characteristic polynomial is
\begin{eqnarray*} p(\lambda)&=&\det(\lambda I-AD)=\left(\begin{matrix}\lambda&-a_1&0&0&0\\
a_2&\lambda&a_2&0&0\\
0&a_3&\lambda&-a_3&0\\
0&0&a_4&\lambda&a_4\\
0&0&0&-a_5&\lambda-a_5\\
\end{matrix}\right)\\
&=&\lambda^5-a_5x^4+(a_1a_2+a_2a_3+a_3a_4+a_4a_5)x^3-(a_1a_2a_5+a_2a_3a_5+a_3a_4a_5)x^2\\
&=&+(a_1a_2a_3a_4+a_1a_2a_4a_5+a_2a_3a_4a_5)x-a_1a_2a_3a_4a_5.
\end{eqnarray*}
Let
$$f(\lambda)=(\lambda-b_1)(\lambda-b_2)(\lambda-b_3)(\lambda-b_4)(\lambda-b_5)$$
where $b_k=2\sin\frac{k\pi}{11},k=1,2,3,4,5$. Now we show that $p(\lambda)$ and $f(\lambda)$ are have the same coefficient for each $x^k$, $k=0,1,2,3,4$ and hence $b_k,k=1,2,3,4,5$ are the eigenvalues of $AD$. For simplicity, we just show that the constant terms of these two polynomials and the coefficients of $x^4$ are the same, respectively, namely.
$$ b_1b_2b_3b_4b_4b_5=a_1a_2a_3a_4a_5, b_1+b_2+b_3+b_4+b_5=a_5 $$
and the rest will be tedious computations.
In fact, since
\begin{eqnarray*}
&&32\cos\frac{\pi}{11}\cos\frac{2\pi}{11}\cos\frac{3\pi}{11}\cos\frac{4\pi}{11}\cos\frac{5\pi}{11}\\
&=&\frac{32\sin\frac{\pi}{11}\cos\frac{\pi}{11}\cos\frac{2\pi}{11}\cos\frac{3\pi}{11}\cos\frac{4\pi}{11}\cos\frac{5\pi}{11}}{\sin\frac{\pi}{11}}\\
&=&\frac{16\sin\frac{2\pi}{11}\cos\frac{2\pi}{11}\cos\frac{3\pi}{11}\cos\frac{4\pi}{11}\cos\frac{5\pi}{11}}{\sin\frac{\pi}{11}}\\
&=&\frac{8\sin\frac{4\pi}{11}\cos\frac{3\pi}{11}\cos\frac{4\pi}{11}\cos\frac{5\pi}{11}}{\sin\frac{\pi}{11}}=\frac{4\sin\frac{8\pi}{11}\cos\frac{3\pi}{11}\cos\frac{5\pi}{11}}{\sin\frac{\pi}{11}}\\
&=&\frac{-4\sin\frac{3\pi}{11}\cos\frac{3\pi}{11}\cos\frac{6\pi}{11}}{\sin\frac{\pi}{11}}=-\frac{2\sin\frac{6\pi}{11}\cos\frac{6\pi}{11}}{\sin\frac{\pi}{11}}=-\frac{\sin\frac{12\pi}{11}}{\sin\frac{\pi}{11}}=1,
\end{eqnarray*}
we have
\begin{eqnarray*}
b_1b_2b_3b_4b_4b_5&=&32\sin\frac{\pi}{11}\sin\frac{2\pi}{11}\sin\frac{3\pi}{11}\sin\frac{4\pi}{11}\sin\frac{5\pi}{11}\\
&=&(\tan\frac{\pi}{11}\tan\frac{2\pi}{11}\tan\frac{3\pi}{11}\tan\frac{4\pi}{11}\tan\frac{5\pi}{11})(32\cos\frac{\pi}{11}\cos\frac{2\pi}{11}\cos\frac{3\pi}{11}\cos\frac{4\pi}{11}\cos\frac{5\pi}{11})\\
&=&a_1a_2a_3a_4a_5.
\end{eqnarray*}
Using that
$$ \sum_{k=1}^N\sin k\theta=\frac{1}{2}\cot\frac{\theta}{2}-\frac{\cos(N+\frac{1}{2}\theta)}{2\sin\frac{\theta}{2}} $$
we have
\begin{eqnarray*}b_1+b_2+b_3+b_4+b_5
&=&2(\sin\frac{\pi}{11}+\sin\frac{2\pi}{11}+\sin\frac{3\pi}{11}+\sin\frac{4\pi}{11}+\sin\frac{5\pi}{11})\\
&=&2\cdot\frac{1}{2}\cot\frac{\pi}{22}=\tan(\frac{\pi}{2}-\frac{\pi}{22})=\tan\frac{5\pi}{11}=a_5
\end{eqnarray*}