Sorry if this is a vague question.
I was handed a map between two manifolds, say, $M\to \mathbb{R^n}$. I was indeed able to find an open cover of $M$ and show that there is a homeomorphism between each open set and some open subset of $\mathbb{R^n}$. Proving homeomorphism usually takes me a long time but it's usually doable. But when it comes to showing that each chart is $C^{\infty}$-compatible, in other words, every transition map is smooth, I'm getting nowhere.
The same situation again happened on proving that Grassmannian in the case of $G(2,4)$ has a smooth structure. I identified each open set that covers $G(2,4)$ and proved homeomorphism, but then when it comes to proving the smoothness of transition maps, I get nowhere again. I get the map between two set of matrices and I had no idea how to argue. I think this happens because general theorems on homeomorphism are well-known but smoothness is really different for every situation. But since I am really having trouble proving smoothness, I'd like to know if there is any standard way or theorem of showing that the transition map is smooth. Thank you for your answers.