In $\mathbb{R}^n$, under the strictest possible definitions, there is no difference between a vector and a coordinate vector in the standard basis. This is because $\mathbb{R}^n$ is defined to be $n$-tuples of real numbers, and the coordinates of a vector in an $n$-dimensional real vector space is defined to be an $n$-tuple of real numbers. In the standard basis, which uses the following real vectors (not coordinates):
$$\begin{bmatrix}1\\0\\\vdots\\0\end{bmatrix} \qquad \begin{bmatrix}0\\1\\\vdots\\0\end{bmatrix} \qquad
\cdots \qquad
\begin{bmatrix}0\\0\\\vdots\\1\end{bmatrix} \qquad $$
Therefore, the $k^\text{th}$ element of a standard-basis coordinate vector for a real vector in $\mathbb{R}^n$ is precisely the $k^\text{th}$ element of the ($n$-tuple, which is a real) vector.
So on a purely set-theoretic level, these two objects are fundamentally, and precisely, the same object.
In general vector spaces the vectors may be weirder. I don't know how much experience you have with vector spaces, but they can be defined very abstractly. For example, polynomials with complex coefficients of degree less than $n$ form a real vector space, where addition and scalar multiplication act in the way you think they do. And this is one of the most normal vector spaces… they only get weirder from here.
But we know ('we' meaning the the mathematical community--I wouldn't expect you to personally be aware) that any finite-dimensional real vector space (FDRVS) is ''basically the same as'' some Euclidean space. Precisely, the two vector spaces are isomorphic, or with equal precision but with more linear-algebra-y words, there is a bijective linear transformation from any FDRVS to a Euclidean space. And as you might imagine, lists of numbers are easier to wrap our heads around than the crazy things inhabiting most vector spaces, so this is why we are interested in coordinates in the first place.
Therefore, because the distinction between the two ways of thinking is so useful in literally every single other vector space, we typically move those ideas over to $\mathbb{R}^n$. In the process, you realize that a change of basis can be described well in this way. So even in $\mathbb{R}^n$ there is a distinction between a real vector and a coordinate vector, where the coordinates are derived from any basis except the standard basis.
The duality in the definition actually has a relatively significant implication for your question. Both of the kinds of vectors have a geometric interpretation, but we think of them in very different ways.
The easier way to think of is the coordinate vectors. Here, you can choose an arbitrary origin, and then use the basis vectors to "grid" the space. From there you use the coordinate vectors to mark off the tick marks on that grid to find the location of the points corresponding to each of the vectors, and voila, geometry!
But you might notice something a little strange about that construction: you have to put the basis vectors on there, but if you don't have a grid already in place, how is that possible? The answer is that we mark the basis vectors using their real vectors. But the real vectors are lists of numbers. So in fact, $\mathbb{R}^n$ really does come with a basis that is in some sense ''correct'', which is why the standard basis has that name.
A real vector is therefore plotted in exactly the same way as a coordinate vector, except then afterwards you forget that the axes were there. In this sense, the study of real vectors as opposed to their more user-friendly coordinate counterparts is sometimes called coordinate-free.
To be clear, the standard basis is therefore fundamentally different than other bases. To be cute about it, you can't buy an $\mathbb{R}^n$ for your office desk without a standard basis preinstalled. But we only need the standard basis to help us define the actual object that is Euclidean space. Once the space is there, you can choose the elements which are the basis under consideration without knowing how they were created.
This is often said in the following way: Coordinate vectors require axes, and real vectors don't. But remember, since real vectors and coordinate vectors are actually the same in the standard basis, this truism is actually a bit off. Hopefully this explanation helps you to understand the finer points of this distinction.
(In the picture you've shown us, it can't be determined which kinds of vectors are being used because it uses the standard basis. But the dashed lines seem to suggest that the illustrator, at least, was thinking of the coordinate vectors. The biggest clue is the fact that the axes are still there in the picture, and you're not just given three arrows and told what vectors they represent. But this is more likely a pedagogical consideration than anything substantive)