Now that I actually know what "percentage difference" means (it was a term I had not heard used in that way before), I can help answer the OP's question, and maybe also pose and answer a related question. This might help the OP or anyone else who happens to be working with this sort of thing.
So OP's question was: given a particular percentage difference (call it $P$), and two numbers (call them $b$ for big and $s$ for small) with a known fixed total (call it $T$), can we determine what the two numbers must be?
So we can write: $\frac{b-s}{0.5T} \cdot 100 = P$ which may be rearranged to $b-s = \frac{PT}{200}$
This equation can be solved simultaneously with $b+s = T$ by first adding both to isolate $b$:
$2b = \frac{PT}{200} + T$
$b = \frac T{400}(200+P)$
and then subtracting one from the other to isolate $s$. By analogous steps we end up with:
$s = \frac T{400}(200-P)$
Now we have fairly neat expressions for both the numbers. The OP can use these expressions by substituting for $T$ ($100$ as per his requirement in this question) and $P$ as he sees fit.
But we can also make some interesting observations from the form of the expressions. Note that if we require both numbers to be non-negative, we require $P \leq 200$. If we need both numbers to be positive, we need $P < 200$. Otherwise, the smaller number will necessarily be negative.
Let's go a little further. We've dealt with a fixed total ($T$). A reasonable additional question to pose would be to ask what happens if we're asked to deal with a fixed difference ($D$). In other words, what should $b$ and $s$ be to arrive at a particular $P$ given a particular $D$?
We again start from the definition and write:
$\frac{D}{0.5(b+s)}\cdot 100 = P$ which may be rearranged to: $b+s = \frac{200D}{P}$
This can be solved simultaneously with $b-s = D$ in a similar fashion to what we did earlier to yield:
$b = \frac{D}{2P}(200 + P)$
and
$s = \frac{D}{2P}(200 - P)$
Note that we can deduce the same conclusions about the upper bound of $P$ for both numbers to be non-negative (or positive) from this set of equations.
In summary, for a fixed total $T$ and a particular percentage difference $P$:
Bigger number: $\displaystyle b = \frac T{400}(200+P)$
Smaller number: $\displaystyle s = \frac T{400}(200-P)$
And for a fixed difference $D$ and a particular percentage difference $P$:
Bigger number: $\displaystyle b = \frac{D}{2P}(200 + P)$
Smaller number: $\displaystyle s = \frac{D}{2P}(200 - P)$
I did this mainly for my own amusement, but I hope it helps someone at some point.