To answer your question, there is one key property to understand when it comes to quadratics and numbers in general.
The equation is as follows:
$a^2 - 9a + 14 = 0$
Let us first look into the factors of the constant, $14$.
The factors of $14$ are as follows:
$$1, 2, 7, 14$$
It is important to note that in the case of quadratics, you can make use of the negative factors as well. For example, $7$ multiplied by $2$ gives $14$, but so does $-7$ multiplied by $-2$. A positive number multiplied by a positive number always gives a positive number as a result. In addition, a negative number multiplied by a negative number also gives a positive number as a result.
In this case, we can see that the second term, $-9a$, fits nicely with the two factors $-7$ and $-2$. $-7$ and $-2$ multiply to give $14$, and when added together, give $-9$ (since $-7 + (-2) = -7 - 2 = -9$).
Therefore, we can factor the equation as follows:
$$a^2 - 9a + 14 = 0$$
$$a^2 - 7a - 2a + 14 = 0$$
$$a(a - 7) - 2(a - 7) = 0$$
$$(a - 2)(a - 7) = 0$$
From here, it is relatively easy to find the values of $a$ which satisfy the original equation (simply equate each factor to $0$ and solve the resulting equation).
I hope this helps! I'm still new to MSE, so I would really appreciate any and all feedback. Thank you!