Let me try to expand (and fix!) my comment into an answer:
If $a=a_0+\cdots+a_n$, I claim that the similarity
$$
\begin{array}{rccc}
F:&\mathbb{R}^n&\longrightarrow&\mathbb{R}^n\\
&v&\longmapsto& -nv+a
\end{array}
$$
sends $S$ to $B$. To prove this we shall see that $F(a_i)$ lies in all the hyperplanes except for $L_i$, which means that $F(a_i)$ is a vertex of $B$.
Let $j\neq i$, is it true that $F(a_i)\in L_j$? This happens iff $F(a_i)-a_j$ is parallel to the hyperplane defined by $\{a_0,\ldots,a_n\}\setminus\{a_j\}$, which is the hyperplane generated by the $n-1$ vectors $$a_0-a_i,\ldots,\widehat{a_j-a_i},\ldots,a_n-a_i.$$ Adding all of them up gives $a-a_i-a_j-(n-1)a_i=-na_i+a-a_j=F(a_i)-a_j$.