In Problem 1 [Bredon, Topology and Geometry, Chapter II] it reads that a functional structure $F$ on a second countable Hausdorff space defines an $n$-manifold if, and only if, there is a cover with open sets $U$ and functions $f_1,\dots,f_n\in F(U)$ such that $$ g\in F(U)\iff \textrm{there exists $h$ smooth with }g = h\circ(f_1,\dots,f_n). $$ To me the case where $F(U)$ is the set of constant functions is a counterexample for the if part.
Am I missing anything? If not, which additional hypothesis should we add?
A functionally structured space is a topological space $(X,{\cal T})$ along with an assignment $U\mapsto F(U)$ for $U\in\cal T$, where $F(U)$ is subalgebra of $C(X,\mathbb R)$ that satisfies
- $F(U)$ includes all constant functions;
- $V\subseteq U$ and $f\in F(U)\implies f|_V\in F(V)$, and
- $f\colon U\to\mathbb R$, $f|_{U_i}\in F(U_i)$ for all $i\in I$ and $U=\bigcup_{i\in I} U_i \implies f\in F(U)$.