$\newcommand{\Reals}{\mathbf{R}}\newcommand{\RP}{\Reals\mathbf{P}}$This answer aims to get at the underlying geometry rather than providing a specific method, and is long for a comment.
In the hope of meshing notation better with projective geometry, I'm bumping up the dimension, so we're looking to parametrize $n$-dimensional linear subspaces of $\Reals^{n+1}$.
Each non-zero vector $w$ uniquely determines an orthogonal complement $w^{\perp}$, and a unique line through the origin, a.k.a. a point $[w]$ of the projective space $\RP^{n}$. If we care about orientation of $w^{\perp}$, or don't want the hassle of working with equivalence classes of vectors, it's geometrically natural instead simply to normalize $w$, treating $w/|w|$ as a point of the unit sphere $S^{n}$ that spans a ray from the origin.
In my reading of the question, a parametrization is
- (Loosely) a uniform way of writing $w^{\perp}$ as a set of linear combinations using a set of $n$ or more vectors that depend algebraically on $w$, or
- (Precisely) an algebraic mapping $P:S^{n} \times \Reals^{n+m} \to \Reals^{n+1}$ for some integer $m \geq 0$ such that for each unit vector $w$, the "slice" $P(w, \cdot):\Reals^{n+m} \to \Reals^{n+1}$ has image $w^{\perp}$.
To expand on Matthew Leingang's and my comments, and explain why over-completeness is generally needed: We can take $m = 0$ (use the "right" number of coefficients) if and only if $n = 0$, $1$, $3$, or $7$. These are the dimensions for which the sphere $S^{n}$ admits $n$ continuous vector fields $(e_{i})_{i=1}^{n}$ (which by construction may be chosen to be algebraic) whose values are linearly independent at each point. The corresponding parametrization is
$$
P(w, t_{1}, \dots, t_{n}) = t_{1}e_{1}(w) + \cdots + t_{n}e_{n}(w).
$$
We can also take $m = 0$ if we're willing to omit one hyperplane, or to allow our parametrization to be discontinuous at one hyperplane. For instance, away from the "north pole" $N = (0, \dots, 0, 1)$ of the sphere, we can parametrize the sphere by stereographic projection, transfer the Cartesian basis of $\Reals^{n}$ to rational tangent vector fields $(e_{i})_{i=1}^{n}$ on the sphere minus $N$, and proceed as above.
One take-away point is, the problem may be phrased in terms of finding some number of (algebraic) vector fields on the sphere whose values at each point span the tangent space.
What of over-complete parametrizations? First, there is a geometrically-natural choice with $(n+1)$ terms: For each unit vector $w = (w_{i})_{i=1}^{n+1}$, orthogonally project the Cartesian basis $(E_{i})_{i=1}^{n+1}$ into $w^{\perp}$, obtaining the spanning set
$$
e_{j} = E_{j} - (E_{j} \cdot w)w = E_{j} - w_{j}w = (\delta_{ij} - w_{i}w_{j})_{i=1}^{n+1}.
$$
If $t = (t_{i})_{i=1}^{n+1}$ is an arbitrary vector, the resulting parametrization is
$$
v = P(w, t) = t - (t \cdot w)w = \sum_{i=1}^{n+1} t_{i}e_{i}.
$$
This is closely related to the complete parametrization of the question: If some component $w_{j}$ is non-zero, then the $n$ vectors $e_{i}$ with $i \neq j$ span $w^{\perp}$, i.e., we can write $e_{j}$ as a linear combination of the $n$ remaining vectors, and eliminate the term $t_{j}e_{j}$ from the preceding sum.
In $\Reals^{3}$, writing $w = (x, y, z)$, this becomes
\begin{align*}
e_{1}(w) &= (1 - x^{2}, -xy, -xz), \\
e_{2}(w) &= (-xy, 1 - y^{2}, -yz), \\
e_{3}(w) &= (-xz, -yz, 1 - z^{2}).
\end{align*}
The over-complete parametrization of this question, i.e., Did's answer in the linked question, instead uses the $\binom{n+1}{2}$ vectors $e_{ij}(w) = w_{i}e_{j} - w_{j}e_{i}$ with $1 \leq i < j \leq n+1$. If $t = (t_{i})_{i=1}^{n+1}$ is a vector in $\Reals^{n+1}$, then $0 = t \cdot e_{ij}$ for all $i$, $j$ if and only if $0 = w_{i}t_{j} - w_{j}t_{i}$ for all $i$, $j$, if and only if $t$ is proportional to $w$. That is, the vectors $(e_{ij}(w))$ span $w^{\perp}$.
In $\Reals^{3}$, as gIS (OP) notes in the comments, this becomes
\begin{align*}
e_{23}(w) &= (0, z, -y), \\
e_{13}(w) &= (z, 0, -x), \\
e_{12}(w) &= (y, -x, 0).
\end{align*}
I'm not the right person to give a detailed algebro-geometric picture, but the incidence problem for a vector lying in a hyperplane may be formulated like this: If $t$ and $w$ are non-zero vectors, then $t \in w^{\perp}$ if and only if $0 = t \cdot w = \sum_{i} t_{i}w_{i}$. For algebraic geometry, it's preferable to view $t \in \Reals^{n+1}$ and $w^{\perp}$ as an element of the dual space $(\Reals^{n+1})^{*}$. Either way, the incidence condition is invariant under multiplication of either factor by non-zero scalars, so is "naturally" viewed as a quadric hypersurface in the product of projective spaces $\RP^{n} \times \RP^{n}$.
The parametrization question may be viewed as seeking an embedding of this quadric in a larger-dimensional projective space, with lower-degree and lower-dimensional embeddings preferred for simplicity. As the two examples above show, however, there are trade-offs: The first has linearly-many vectors ($n+1$ for an $n$-dimensional space) whose components are quadratic in $w$, while the second has quadratically-many vectors ($\frac{1}{2}n(n+1)$ for an $n$-dimensional space) whose components are linear in $w$.