It is because the hand is dealt without replacement that we can say the probability is $\frac{3}{52}$ right off the bat. This is because since the position of the Ace of Spades does not matter, we can consider the 3 cards to have been dealt all at the same time. As a sanity check:
To calculate the probability that the hand includes the Ace of Spades, we can calculate the probability that the hand does not contain the Ace of Spades and subtract that from 1.
$P(\text{First card not Ace of Spades})=\frac{51}{52}$
$P(\text{Second card not Ace of Spades|First card was not})=\frac{50}{51}$
$P(\text{Third card not Ace of Spades|First and second were not})=\frac{49}{50}$
So $P(\text{Ace of Spades})=1-\frac{51}{52}\frac{50}{51}\frac{49}{50}=\frac{3}{52}$
Had we allowed replacement, the probability would have been $1-\left(\frac{51}{52}\right)^3$ which includes the possibilities of having multiple Ace of Spades in the hand.