$f(x)$ has second derivative on $[0,1]$, and $f(0)=f'(0), f(1)=f'(1)$. Prove that: there exists $\xi\in (0,1)$, s.t. $f(\xi)=f''(\xi)$.
Let $g(x)=\left(f(x)\right)^2-\left(f'(x)\right)^2$, then $g(0)=g(1)=0$. By Rolle's theorem there exists $\xi\in (0,1)$, s.t. $g'(\xi)=2f'(\xi)(f(\xi)-f''(\xi))=0$. If $f'(\xi) \neq 0$ it will work. However, what if $f'(\xi)=0$?
I found a problem almost the same, just adding a condition $f(0)=f'(0)=f(1)=f'(1)=0$. With this condition, we consider a function $h(x)=\dfrac{f(x)+f'(x)}{\mathrm{e}^x}$. Applying Rolle's theorem there exists $\xi\in (0,1)$, s.t. $h'(\xi)=\dfrac{f''(\xi)-f(\xi)}{\mathrm{e}^\xi}=0$, thus satisfying the requirement.
So is the original problem correct without the condition?