You can use induction: on $n$. First note that the inequality is an equality when $n = 1$, which is the base case.
Next suppose that the inequality holds for $n = k$. Then let $x_{k + 1} \in [0, 1]$ be arbitrary and observe that then using the induction hypothesis we have
$$
1 - \sum_{i = 1}^{k + 1} x_i
= \left(1 - \sum_{i = 1}^k x_i\right) - x_{k + 1}
\leq \prod_{i = 1}^k ( 1 - x_i) - x_{k + 1}.
$$
But since each $x_i \in [0,1]$ then $1 - x_i \in [0,1]$, and therefore $\prod_{i = 1}^k ( 1 - x_i) \in [0, 1]$. Thus $x_{k + 1} \geq x_{k + 1}\prod_{i = 1}^k ( 1 - x_i)$ and so we also have (factoring out the entire product $\prod_{i = 1}^k ( 1 - x_i)$)
$$
\prod_{i = 1}^k ( 1 - x_i) - x_{k + 1}
\leq \prod_{i = 1}^k ( 1 - x_i) - x_{k + 1} \prod_{i = 1}^k ( 1 - x_i)
\leq (1 - x_{k + 1}) \prod_{i = 1}^k ( 1 - x_i)
= \prod_{i = 1}^{k + 1} ( 1 - x_i).
$$
Putting these two inequalities together, this completes the proof.