By definition it means for all $x\in \mathbb{R}$, that
$$\mathbb{P}(X_n \leq x) \rightarrow \mathbb{P}(X \leq x) \quad \text{ for $n\rightarrow \infty $}.$$
Or more concretely, that there for any $\epsilon >0$ exists $N\in \mathbb{N}$ such that
$$|\mathbb{P}(X_n \leq x) - \mathbb{P}(X \leq x)| < \epsilon \quad \text{ for all $n\geq N$.}
\tag{1}$$
This is very useful. For instance if we want to compute $\mathbb{P}(a<X_n \leq b)$ for some large $n$, then we can note that
\begin{align*}
\mathbb{P}(a<X_n \leq b) &=F_n(b)-F_n(a) \\
&= F(b)-F(a) +\underbrace{(F_n(b)-F(b)) +(F(a)-F_n(a))}_{\text{error term}}
\end{align*}
Where the error term can be made arbitrarily small because of $(1)$. For example consider $X_n \sim \operatorname{Poisson}(n)$, then it is well known that $\frac{X_n - n}{\sqrt{n}}$ converges in distribution towards $N(0,1)$, so for large $n$ we have that
$$\mathbb{P}(a < \frac{X_n - n}{\sqrt{n}} \leq b) \approx \Phi(b)-\Phi(a) = \frac{1}{\sqrt{2\pi}} \int_a^b e^{-\frac{x^2}{2}} \: dx$$
In fact we can even conclude
\begin{align*}\mathbb{P}(a < X_n \leq b) &= \mathbb{P}(\frac{a-n}{\sqrt{n}} < \frac{X_n - n}{\sqrt{n}}\leq \frac{b- n}{\sqrt{n}}) \\
&\approx \Phi(\frac{b-n}{\sqrt{n}}) - \Phi(\frac{a-n}{\sqrt{n}}) \\
&= \frac{1}{\sqrt{2\pi n}}\int_a^b e^{-\frac{(x-n)^2}{2n}} \: dx,
\end{align*}
which does mean that the $\operatorname{Poisson}(n)$ distribution is close to the $N(n,n)$ distribution for large $n$.