We deal here with the notion of falling factorial.
Let us first rewrite your binomial coefficient in a simpler way, using classical formula: $\binom{N}{P}=\binom{N}{N-P}$:
$$\binom{n/4}{n/4-5}=\binom{n/4}{n/4-(n/4-5)}=\binom{n/4}{5}\tag{1}$$
A falling factorial is (indeed) defined as a polynomial with consecutive integer roots beginning at $0$ ; more precisely:
$$x_{(N)}:=x(x-1)(x-2) \cdots (x-N+1)\tag{2}$$
with the property:
$$\dfrac{x_{(N)}}{N!}=\binom{x}{N}\tag{3}$$
(this definition and this property can be found in the Wikipedia reference given above ; please note that this definition/property extends a property that we know as valid for integer values of $x$).
Setting $x=n/4, N=5$ (take care not to mix $n$ and $N$) and using (1),(2), and (3), it is easy to establish your identity.
Remark: you will see in the Wikipedia article the dual concept of rising factorial.