The Catalan numbers generating function
power series multiplied by $x$ is
$$ \frac{1-\sqrt{1-4x}}2 = \sum_{n=0}^\infty C_n x^{n+1}. \tag{1} $$
Substitute $\,y\,$ for $\,x\,$ and subtract both equations to get
$$ \frac{1-\sqrt{1-4y}}2- \frac{1-\sqrt{1-4x}}2 =
\sum_{n=0}^\infty C_n (y^{n+1}-x^{n+1}). \tag{2} $$
Divide both sides by $\,y-x\,$ and express
$\,\frac{y^{n+1}-x^{n+1}}{y-x}\,$ as a sum to get
$$ \frac{\sqrt{1-4x}-\sqrt{1-4y}}{2(y-x)} =
\sum_{n=0}^\infty C_n \frac{y^{n+1}-x^{n+1}}{y-x} =
\sum_{n=0}^\infty C_n\sum_{m=0}^n y^m x^{n-m}. \tag{3} $$
Simplify the left side and change summation indices on the right
to get
$$ \frac2{\sqrt{1-4y}+\sqrt{1-4x}} = \sum_{k=0}^\infty\sum_{n=0}^\infty
C_{n+k}\,y^n x^k. \tag{4}$$
Substitute $\,y=\frac14\,$ and expand $\,\frac2{\sqrt{1-4x}}\,$
with binomial coefficients to get
$$ \frac2{\sqrt{1-4x}} = \sum_{k=0}^\infty 2\binom{2k}{k}x^k =
\sum_{k=0}^\infty\sum_{n=0}^\infty\frac{C_{n+k}}{4^n} x^k. \tag{5}$$
Finally, equate corresponding coefficients of $\,x^k\,$ to get
$$ 2\binom{2k}{k} = \sum_{n=0}^\infty\frac{C_{n+k}}{4^n}. \tag{6} $$