I know that the span of the vectors in the tangent space at the identity of a Lie Group is isomorphic to the span of the left-invariant vector fields over the Lie Group. It seems to me (a physicist) so much easier to consider a Lie Algebra by this $T_{e}$ tangent space at the identity, so I'm wondering why groups resources define Lie Algebras using left-invariant vector fields at all?
My only guess is that left-invariant vector fields are required in order to uniquely specify the integral curves used in defining the exponential map?