$$y = \arccos(\sin(2x))$$
I can't see why it can't be used in Fourier expansion series. It seems to me that it satisfies all the Dirichlet properties:
Periodic ? Yes, $\pi $.
Continuous ? Yes
Finite number of max/mín in a period? Yes, there is one maximum and zero mínimum.
Module of the integral converges? Yes,$\frac{\pi^2}{2}$
So, what is the problem with the function? Why can't it be used for Fourier expansion?