This is a Fredholm integral equation of the second kind for the unknown function $F_1$. Namely, since $F_2 = f - F_1$, the function $F_1$ must satisfy
$$
F_1(x) = f(x) + \int_a^b K(x,t) F_1(t) \, dt \, .
$$
Usually there is a unique $F_1$ that solves the problem, but if the integral operator has the eigenvalue -1, i.e. if there is a non-trivial function $g$ such that $g(x) + \int_a^b K(x,t) g(t) \, dt = 0$ , there may be infinitely many solutions or none at all, depending on $f$.
You can't choose $F_1$, you must solve for it. After $F_1$ has been found, also $F_2 = f-F_1$ is uniquely determined. Of course at that point you can split $F_1 = f_1 + f_2, F_2 = f_3 + f_4 + f_5$ or whatever you like. But $F_1$ and therefore also $F_2$ cannot be chosen arbitrarily.