To be clear, only one group is being formed,and order does not matter. The only thing making the answer NOT 6 choose 3 is that two of the people cannot both be in the group at the same time. How to deal with that is my question.
edit: so I had an idea, since every person has a 1/2 chance of getting in the group, there is a 1/4 chance of any two people being on the group. Meaning that there is a 1/4 chance that the two people who can't be together are, meaning that the answer should be 3/4s of 6 choose 3 right?