In a Dynkin diagram there is a special involution often constructed as follows: Let $C$ be the Weyl chamber corresponding to our diagram. There is a unique element of the Weyl group $w$ for which $wC = -C$. Then $-w$ preserves $C$ and so permutes the simple roots giving us a diagram automorphism (indeed an involution). For most diagrams this is just the identity except $D_n$, ($n$ odd) where it swaps the two end nodes and $A_n$, $E_6$ where it is the natural symmetry of the diagram.
This involution is quite handy as applying it to decorated Dynkin (or Satake) diagrams capture the notion of duality. Firstly, if we use use the diagram to indicate a representation by placing integers over the nodes, applying the involution gives us the dual representation. Secondly, if we represent parabolic subalgebras (or their conjugacy classes) by crossing nodes on the diagram, the involution gives us the dual class containing the complementary/opposite parabolic subalgebras.
I have seen this involution referred to in many places but cannot recall ever seeing a name for it. Does anyone know of one?