You're not starting out the problem correctly. Whenever you do a proof by induction, your base case should always be the lowest number in the set you're working with. In this case, we're working with $n \geq 0$. The lowest number in that set of nonnegative integers is $n=0$, so that's what your base case should be about. (Surely you can start at $n=1$, but then you'd also have to make a case where $n=0$ as well.)
Also, $n=1$ works because
$$\displaystyle\sum_{k=0}^{1} \frac{1}{2^k} = \frac{1}{2^0} + \frac{1}{2^1} = \frac{3}{2}$$
and
$$2 - \frac{1}{2^1} = \frac{3}{2}.$$
(Answer) The given statement you're trying to prove is true.
Base Step. If $n=0$, then
$$\sum_{k=0}^{0}\frac{1}{2^{k}}=\frac{1}{2^{0}}=1$$
and
$$2-\frac{1}{2^{0}} = 1.$$
Inductive Step. Fix some nonnegative integer $m \geq 0$ and suppose
$$\sum_{k=0}^{m}\frac{1}{2^{k}}=2-\frac{1}{2^{m}}.$$
Then
$$\sum_{k=0}^{m+1}\frac{1}{2^{k}}=\sum_{k=0}^{m}\frac{1}{2^{k}}+\frac{1}{2^{m+1}}\ =\ 2-\frac{1}{2^{m}}+\frac{1}{2^{m+1}}.$$
I think you can take it from here. Does that help?