Since $\mathbb{Z}$ is commutative ring with unity and A is ideal of R=$\mathbb{Z}$ then use this result R/A is field if and only if A is maximal ideal.
Here $A=\left\langle 6 \right\rangle$(generated by 6) is not maximal ideal.
I feel still you are not understand
here $\left\langle 6 \right\rangle \subset \left\langle 2 \right\rangle \subset \mathbb{Z}$ so it is not maximal it implies that$ \mathbb{Z}/ 6\mathbb{Z}$ is not field.
Additional Ans. of below comments:
For example, Let us consider $\mathbb{Z}/ 4\mathbb{Z}=\{0+4\mathbb{Z},1+4\mathbb{Z},2+4\mathbb{Z},3+4\mathbb{Z}\}$
If possible suppose there is $a+4\mathbb{Z} \in \mathbb{Z}/4\mathbb{Z}$
such that $(2+4\mathbb{Z})(a+4\mathbb{Z})=(1+4\mathbb{Z})$
$(2+4\mathbb{Z})(a+4\mathbb{Z})=2.a+2.4\mathbb{Z}+4\mathbb{Z}.4\mathbb{Z}+a.4\mathbb{Z}$
but all the other elements except '$2.a$' will absorbed in $4\mathbb{Z}$
So we get $2.a+4\mathbb{Z}=(1+4\mathbb{Z})$
it implies that $2.a-1 \in 4\mathbb{Z}$
that is not possible.
therefore $2+4\mathbb{Z}$ has no inverse in $\mathbb{Z}/4\mathbb{Z}$