In infix notation, the expression $x + y + z$ is technically ambiguous because it could refer to either $(x + y) + z$ or to $x + (y + z)$. Of course, we do this precisely because we like the ambiguity as these two expressions yield the same result and we don’t want to think about how to place the parentheses all the time.
When translating them to postfix notation, you need to make a choice, though. The first option leads to $x~ y + z~ +$ and the second to $x~y~ z + +$.
Note that this is precisely your example with
$$\begin{align*}
x &= a\\
y &= b \times (c + d) = b~c~d + \times \\
z &= e \times f = e~f~ \times
\end{align*}$$
So the order of operations (multiplication before addition) really does not have much to do with it.