You should approach this by breaking it down into each step.
Step 1: The base case.
You are trying to prove that it is true for $n \geq 4$, and so your base case should be for the lowest integer satisfying the inequality (4). This is as simple as direct computation of the two values. This should be true (it is since $81 > 80$).
Step 2: Assume that it is true for $n=k$. That is to say, assume $3^k > 5k^2$.
Step 3: $n = k + 1$
$\text{RHS} = 5(k+1)^2 = 5(k^2 + 2k + 1)$
As Manifoldski pointed out, $(n + 1)^2 < 3n^2$ for $n>2$
$\implies \text{RHS} < 3(5k^2)$
Since we have assumed step 2,
$\implies \text{RHS} < 3(5k^2) < 3(3^k) = 3^{k+1}$
$\implies \text{RHS} = 5(k+1)^2 < 3^{k+1} = \text{LHS}$
And thus the inequality holds for $n = k + 1$, given that it holds for $n = k$.
Since the inequality holds for $n = 4$, and if it holds for $n = k$, it also holds for $n = k + 1$, by induction, the inequality holds for all $n\in \mathbf{N},n\geq4$.