Picking examples to show it's not injective is a fine way to do so. The simplest example to pick, two values $a,b$ such that $f(a) = 0$ and $f(b) = 0$, turns out to work fine.
If your initial guesses for which $c$ to use when trying to find two solutions to $f(x) = c$ don't work, you can appeal to your general approaches to understanding functions to try and gain insight as to which values would be useful to pick for $c$, such as graphing the function via calculator, or the techniques you've learned for plotting by hand.
The things that make it visually obvious that $f(x)$ is not injective, however, have a more direct translation to a mathematical argument than guessing a value for $c$. The same for surjectivity, incidentally:
See if you can prove the following two theorems:
If $f$ is an injective differentiable function, then $f'(x) \geq 0$ for all $x$, or $f'(x) \leq 0$ for all $x$.
If $f$ is a continuous function $\mathbf{R} \to \mathbf{R}$, then it is surjective if and only if it has no upper bound and no lower bound.