First, the statement needs to be slightly amended. Recall that the differential $df_{p}\colon \operatorname{T}_{p}S^{2} \to \operatorname{T}_{f(p)}S^{2}$ is a linear map. In particular, $df_{p}(\mathbf{0}) = \mathbf{0}$. We thus have a trivial counterexample to your assertion. What is true, however, is that this is the only counterexample, i.e., that $df_{p}(v) \neq \mathbf{0}$ provided that $v \neq \mathbf{0}$. I prove this as follows.
Let us consider the circumstances under which $(f \circ \alpha)'(0) = \mathbf{0}$. I first substitute the formula for $f$ to obtain a formula for $f \circ \alpha$.
$$ t \mapsto \begin{pmatrix} \cos(30^{\circ}) \alpha_{1}(t) + \sin(30^{\circ}) \alpha_{2}(t) \\ \sin(30^{\circ}) \alpha_{1}(t) - \cos(30^{\circ}) \alpha_{2}(t) \\ \alpha_{3}(t) \end{pmatrix}. $$
The key is to the rest of this computation is to note that $f$ is actually linear; the trigonometric coefficients are constant. The derivative is therefore a quick application of the chain rule.
$$ (f \circ \alpha)'(0) = \begin{pmatrix} \cos(30^{\circ}) \alpha_{1}'(0) + \sin(30^{\circ}) \alpha_{2}'(0) \\ \sin(30^{\circ}) \alpha_{1}'(0) - \cos(30^{\circ}) \alpha_{2}'(0) \\ \alpha_{3}'(0) \end{pmatrix} = \begin{pmatrix} \cos(30^{\circ}) & \sin(30^{\circ}) & 0 \\ \sin(30^{\circ}) & -\cos(30^{\circ}) & 0 \\ 0 & 0 & 1 \end{pmatrix} \begin{pmatrix} \alpha_{1}'(0) \\ \alpha_{2}'(0) \\ \alpha_{3}'(0) \end{pmatrix}. $$
Since the matrix has determinant $-1$, the derivative $(f \circ \alpha)'(0)$ vanishes if and only if $\alpha'(0) = \mathbf{0}$, i.e., $v = \mathbf{0}$. This proves the amended assertion.
In closing, let me add two remarks.
- We expect the result because $f$ is a rotation of the sphere about the $z$-axis by 30 degrees composed with a reflection across the $x$-$z$ plane, and so regular curves remain regular.
$$ \begin{pmatrix} \cos(30^{\circ}) & \sin(30^{\circ}) & 0 \\ \sin(30^{\circ}) & -\cos(30^{\circ}) & 0 \\ 0 & 0 & 1 \end{pmatrix} = \begin{pmatrix} 1 & 0 & 0 \\ 0 & -1 & 0 \\ 0 & 0 & 1 \end{pmatrix} \begin{pmatrix} \cos(-30^{\circ}) & -\sin(-30^{\circ}) & 0 \\ \sin (-30^{\circ}) & -\cos(-30^{\circ}) & 0 \\ 0 & 0 & 1 \end{pmatrix}. $$
- Note that the matrix with determinant $-1$ above is the Jacobian matrix of $f$ viewed as a map from $\mathbf{R}^{3} \to \mathbf{R}^{3}$.