I prefer to use fractions of all-space (ie the sphere = 1), rather than solid radians. This means that the solid angle occupied by a point on a polyhedron edge is the same as its dihedral angle, and the point on the meeting of faces in general are also likewise such.
I am not exactly sure if there is a means when one is given general vectors. Even the specific cases (like a regular simplex in N dimensions) are hard to find without fancy calculus. To this end, one tries to fill the inside of a sphere with a solid, and fill the exterior (just outside the unit sphere) with a least-enclosing solid.
Currently, of the simplex, it is known that the volume $S_n$, lies $1 < S_{n-1} < S_{n} < \frac 12\sqrt{n}$, of a volume of an orthotope whose diagonals are the radius of the sphere, or $1/n!$ of the solid radian. The packing of spheres in $N=8$ and $N=24$ are dense enough to fall in this range $S_8 > 1.33, \;\; S_{24} > 1.6 $. The volume of the interior solid, is $\sqrt{2^n/n}$ of the simplex inscribed in the sphere. At eight dimensions, this means $5 \frac 13$ of simplex, but we can get as many as $7 \frac 19$ times this volume in there, the extra lieing within 1/30 of the surface.
The solid angle at the orthotope converges on $2^n/2\sqrt{n}$ of the simplex, but only E8 has an integer number of simplices (17280), and orthotopes (2160) at a vertex.
The main problem is that even for the current estimate for an interior figure (which lies within 3% of the surface), raising something like $1.03^n$ can get quite large for even small values of $n$, eg $1.03^{24}=2.032$. This means that there is nearly as much room in the orange-peel (the outer 30/31 part), as there in the orange! The errors come rediably large.
There are of course, vectors that form the corner groups of symmetries, which allow one to experiment with the processes. For example, the vectors $(1,0,0,..), (1,1,0,..), ... (1,1..1)$, form a simplex whose volume is $1/(2^n. n!)$, this is the symmetry of a measure polytope.