(Instead of just giving a counterexample, let's walk through the approach you should take in a situation like that.)
This requires simply to verify the three axioms of topology. Let's take any chain of topologies, not just countably infinite. So we have $\tau=\bigcup_{i\in I}\tau_i$ which are an increasing chain of topologies on $X$.
Recall the axioms.
- $\varnothing$ and $X$ are open;
- finite intersections are open; and
- arbitrary unions are open.
The first is obviously true, and the second is also fairly easy, given finitely many $U_i$ there are $\tau_i$ such that $U_i\in\tau_i$. Therefore in the maximal of the $\tau_i$'s all the sets appear, and so does their intersection.
But what about the third? Given an arbitrary collection of open sets, if we could have bound it in the chain, i.e. find a topology which contains them all, then we were done. But what if we choose one from each topology (which didn't appear before)? Then we can get in trouble. Let's use this to construct a counterexample!
Consider $X=\Bbb R$, and let $\tau_i$ for $i\in\Bbb N$ be the topology which is generated from declaring that $\{j\}$ for $j<i$ are open sets. So $\tau_0$ is the trivial topology, and $\tau_1$ contains only $\{0\}$ as a nontrivial open set, and so on.
Let $\tau$ be the union of $\tau_n$, and consider the collection $\{\{n\}\mid n\in\Bbb N\}$. Every $\{n\}\in\tau_n$, so this entire collection is a collection of elements of $\tau$. But its union is $\Bbb N$. It's not hard, at all, to show that all the open sets in $\tau_n$ are finite, for every $n$ (except $X$ of course). Therefore in the union there is no infinite open set (again, except $X$). So $\Bbb N$ is not in $\tau$, so $\tau$ is not a topology.