$$
\begin{align}
\lim_{t\to\infty}te^t\int_t^\infty\frac{e^{-s}}{s}\,\mathrm{d}s
&=\lim_{t\to\infty}t\int_0^\infty\frac{e^{-s}}{t+s}\,\mathrm{d}s&&s\mapsto t+s\\
&=\lim_{t\to\infty}\int_0^\infty\frac{e^{-s}}{1+s/t}\,\mathrm{d}s\\
&=\int_0^\infty e^{-s}\,\mathrm{d}s&&\begin{array}{}\text{Dominated}\\ \text{Convergence}\end{array}\\[8pt]
&=1
\end{align}
$$
If an asymptotic expansion is desired, we can use the fact that $\int_0^\infty s^n\,e^{-s}\,\mathrm{d}s=n!$ to get
$$
\begin{align}
te^t\int_t^\infty\frac{e^{-s}}{s}\,\mathrm{d}s
&=\int_0^\infty\frac{e^{-s}}{1+s/t}\,\mathrm{d}s\\
&=\int_0^\infty\left(1-\frac{s}{t}+\frac{s^2}{t^2}-\frac{s^3}{t^3}+\dots\right)\,e^{-s}\,\mathrm{d}s\\
&=0!-\frac{1!}{t}+\frac{2!}{t^2}-\frac{3!}{t^3}+\dots
\end{align}
$$
As with most asymptotic expansions, this converges nowhere.