You need to have $x^2-9\ge 0$, not $x^2-9<0$. This is $(x-3)(x+3)\ge 0$, which is the case when
- one of $x-3$ and $x+3$ is $0$,
- both $x-3$ and $x+3$ are positive, or
- both $x-3$ and $x+3$ are negative.
In all other cases $(x-3)(x+3)$ is negative, which is precisely what you don’t want.
The first of these happens when $x=3$ or $x=-3$.
The second happens when $x>3$ and $x>-3$; of course if $x>3$, then automatically $x>-3$, so this happens when $x>3$.
And the third happens when $x<3$ and $x<-3$; this time we notice that if $x<-3$, then automatically $x<3$, so this happens when $x<-3$.
Putting the pieces together, we see that $x^2-9\ge 0$ when $x\le -3$ or $x\ge 3$.
With practice, however, you should come to realize that if $a\ge 0$, then $x^2\ge a^2$ if and only if $|x|>\sqrt{a}$. Here that means that $|x|\ge 3$, which means that $x$ is at least as far away from $0$ as $3$ is, i.e., that $x\le -3$ or $x\ge 3$.