Let $S$ and $W$ be complex and finite-dimensional vector spaces. In the following we consider the obvious action of $\mathrm{End}_{\mathbb C}(S)$ on $S$ and $S\otimes W$. Since $$\forall A\in\mathrm{End}_{\mathbb C}(W):1\otimes A\in\mathrm{End}_{\mathrm{End}_{\mathbb C}(S)}(S\otimes W)$$ we can ask whether the function \begin{align} \mathrm{End}_{\mathbb C}(W)&\to\mathrm{End}_{\mathrm{End}_{\mathbb C}(S)}(S\otimes W)\\ A&\mapsto 1\otimes A \end{align} is bijective. Injectivity should be clear, so the main issue should be surjectivity.
Motivation: AFAIU this is claimed without proof in proposition 3.27 of Heat Kernels and Dirac Operators.