Suppose you have a manifold $M$ and a finite set $S = \{x_1, \ldots, x_n\}$ of points in the same connected component of $M$. I am looking for criteria that ensures $S$ is contained in a connected chart.
Partial progress:
- $n = 2$: by the discussion in comments, there exists an embedded arc from $x_1$ to $x_2$. A tubular neighborhood will be the desired chart.
- $M$ compact, $x_i$'s very close: Take the lebesgue number $r$ of an atlas of $M$, with respect to the distance induced by some riemannian metric on $M$. If $d(x_1, x_i) < r$ for $i=2, \ldots, n$, then $S \subset B_r(x_1)$ which is in a chart by the lebesgue number property.