Note: Errors existed in the previous version of this post. I'm including this notification to illuminate that the errors were fixed.
Well, the functional equation immediately tells us that
$$
\frac{\zeta(s)}{\zeta(1-s)} = 2^s \pi^{s-1} \sin \left( \frac{\pi s}{2} \right) \Gamma(1-s)
$$
Ultimately, the key to these for $s=\frac{2n+1}{2}$ lies in the value of
$$
\Gamma(1-s) = \Gamma \left( 1-\frac{2n+1}{2} \right)
$$
One might wonder why I chose this expression instead of that of your denominator. The gamma function has a reflection formula (see Wikipedia),
$$
\Gamma(s) \Gamma(1-s) = \frac{\pi }{\sin(\pi s)} \text{ for non-integer } s
$$
So we then have
$$
\Gamma \left( 1-\frac{2n+1}{2} \right)
= \frac{\pi }{\sin \left( \pi \frac{2n+1}{2} \right) \Gamma \left( \frac{2n+1}{2} \right)}
$$
This sine term is $(-1)^n$. It is known that
$$
\Gamma \left( \frac{2n+1}{2} \right)
= \Gamma \left( n + \frac 1 2 \right)
= \frac{(2n-1)!!}{2^n} \sqrt \pi
$$
(see Wikipedia).
Therefore,
$$
\Gamma \left( 1-\frac{2n+1}{2} \right)
= \frac{(-1)^n \pi }{\frac{(2n-1)!!}{2^n} \sqrt \pi}
= \frac{(-1)^n 2^n \sqrt \pi }{ (2n-1)!! }
$$
Hence, using the functional equation and simplifying,
$$\begin{align*}
\frac{\zeta\left(\frac{2n+1}{2}\right)}{\zeta\left(1-\frac{2n+1}{2}\right)}
&= 2^{\frac{2n+1}{2}} \pi^{\frac{2n+1}{2}-1} \sin \left( \frac{\pi}{2} \frac{2n+1}{2} \right) \frac{(-1)^n 2^n \sqrt \pi }{ (2n-1)!! } \\
&= 2^{\frac{4n+1}{2}} \pi^{n} \sin \left( \frac{2n+1}{4} \pi \right) \frac{(-1)^n }{ (2n-1)!! } \\
\end{align*}$$
One more simplification of sorts can be made: just by looking at what numbers it outputs,
$$
\sin \left( \frac{2n+1}{4} \pi \right)
= \frac{(-1)^{\lfloor n/2 \rfloor} }{\sqrt 2}
$$
so using this we get
$$
\frac{\zeta\left(\frac{2n+1}{2}\right)}{\zeta\left(1-\frac{2n+1}{2}\right)} = \frac{(-1)^{n+\lfloor n/2 \rfloor} (4\pi)^n }{ (2n-1)!! }
$$
Not that I can justify this one more than "by playing around", but we can see that
$$
(-1)^{n+\lfloor n/2 \rfloor}
= (-1)^{\lceil n/2 \rceil}
$$
to simplify just a tad more:
$$
\frac{\zeta\left(\frac{2n+1}{2}\right)}{\zeta\left(1-\frac{2n+1}{2}\right)} = \frac{(-1)^{\lceil n/2 \rceil} (4\pi)^n }{ (2n-1)!! }
$$