This short manuscript by Francisco G. Montoya presents and proves a general formula that gives the rotor (up to a sign change) that effects a certain rotation transformation, from a given vector basis and its rotated image. Although I could follow the steps, I can't see how one would come up with summations (3) and (6) as starting points out of the blue. Is there a certain intuition that could take us from the defining equations of a rotor transformation ($u \to R u R^\dagger$) to the summations presented?
The author begins with summation (3), given by
$$\sum_{k=1}^n \sigma_k R^\dagger \sigma_k \quad,$$
where the $\sigma_k$ are the original, non-rotated basis vectors, and
$$R^\dagger = \alpha - \sum_{i<j}^n \beta_{ij} \sigma_{ij} \quad,$$
just the definition of a rotor.
He shows that the first summation is
$$\sum_{k=1}^n \sigma_k R^\dagger \sigma_k = 4 \alpha + (n-4) R^\dagger \quad.$$
He then forms
$$\sum_{k=1}^n\mu_k \sigma _k = R \sum_{k=1}^n \sigma_k R^\dagger \sigma_k = 4\alpha R + (n-4) \quad,$$
where the $\mu_k$ are the rotated $\sigma_k$. So
$$4\alpha R = \sum_{k=1}^n\mu_k \sigma _k + (4-n) \quad,$$
which means $R$ is a scalar multiple of $\sum_{k=1}^n\mu_k \sigma _k + (4-n)$ (remember that $\alpha$ is the scalar part of $R$). Enforcing the constraint that $\lVert R \rVert = 1$ means that
$$R = \pm \frac{\sum_{k=1}^n\mu_k \sigma _k + (4-n)}{\lVert \sum_{k=1}^n\mu_k \sigma _k + (4-n) \rVert} \quad.$$
(I included the $\pm$).
My question boils down to what thought process sensibly connects a rotor's definition and action on a vector to conjuring up the summation
$$\sum_{k=1}^n \sigma_k R^\dagger \sigma_k \quad,$$
which is the key to the whole proof. I could see how one might come up with the second summation, $\sum_{k=1}^n \mu_k \sigma_k$, after having been presented the first one, but it still looks like a fairly non-obvious development.