Taking the circumradius as the length unit, you can assume WLOG that the triangle is inscribed into the unit circle.
You can furthermore assume that the vertices are
$$1,e^{ib},e^{ic}\tag{1}$$
The circumcenter is therefore the center of the unit circle, i.e., origin point $0$.
Constraining the centroid $\frac13(1+e^{ib}+e^{ic})$ to coincide with the circumcenter is equivalent to write :
$$1+e^{ib}+e^{ic}=0 \tag{2}$$
Intuitively, (2) is possible iff points (1) constitute an equilateral triangle, but we need to prove it. Here is a way. Taking real and imaginary parts in (2), we get :
$$\begin{cases}\cos b +\cos c &=&-1\\
\sin c &=&-\sin b \end{cases} \tag{3}$$
Squaring the second equation in (3), we deduce that
$$\cos b =\pm \cos c. \tag{4}$$
Plugging (4) into the first equation of (3), we see that the single possibility is with the $+$ sign in (4), giving :
$$2 \cos b=-1 \iff \cos b= \cos \frac{2 \pi}{3} \iff \text{either} \ b=\frac{2 \pi}{3} \ \& \ c=\frac{4 \pi}{3}$$
or a similar result by exchange of $b$ and $c$.
$$1,e^{ib},e^{ic}$$
Can you take it from here ?
– Jean Marie Oct 29 '23 at 08:49