More generally, if $p$ is a polynomial and $\lambda$ is a characteristic root of $A$, then $p(\lambda)$ is a characteristic root of $p(A)$. One way to see this
is that we can write the polynomial $p(x)$ as $p(\lambda) + g(x) (x - \lambda)$ for some polynomial $g(x)$ (i.e. $p(x) - p(\lambda)$ is divisible by $x - \lambda$), and then $p(A) = p(\lambda) I + g(A) (A - \lambda I)$. So
$p(A) - p(\lambda) I = g(A) (A - \lambda I)$ must be singular (if you want to understand this on the level of determinants, $\det(p(A) - p(\lambda) I) = \det(g(A)) \det(A - \lambda I) = 0$), which says
$p(\lambda)$ is a characteristic root of $p(A)$.
Now in your case $p(x) = x^n - 1$, and $p(A) = 0$. The only characteristic root of the $0$ matrix is $0$, so for every characteristic root $\lambda$ of $A$ we must have $p(\lambda) = 0$.