As other answers point out, there are perfectly straightforward approaches to this problem by working directly from the definition of $R$. In this case, however, there is also a more visual approach. For $\langle x,y\rangle,\langle s,t\rangle\in\Bbb R\times\Bbb R$ we have $\langle x,y\rangle\mathbin{R}\langle s,t\rangle$ if and only if $2(x-s)=y-t$, which in turn is equivalent to $2x-y=2s-t$. Thus, we could just as well have defined $R$ by saying that
$$\langle x,y\rangle\mathbin{R}\langle s,t\rangle\quad\text{if and only if}\quad 2x-y=2s-t\;.$$
Let $\alpha$ be any real number. If $x,y,s,t\in\Bbb R$ satisfy $2x-y=\alpha$ and $2s-t=\alpha$, then automatically $2x-y=2s-t$ and $\langle x,y\rangle\mathbin{R}\langle s,t\rangle$. What are the pairs $\langle s,t\rangle\in\Bbb R\times\Bbb R$ such that $2s-t=\alpha$? They’re exactly the points on the line $2x-y=\alpha$ or, if you prefer, $y=2x-\alpha$. Each possible value of $\alpha$ gives such a line, and all of the points on any one of those lines are in the relation $R$ to one another. Conversely, if $\langle x,y\rangle\mathbin{R}\langle s,t\rangle$, then $2x-y=2s-t=\alpha$ for some $\alpha\in\Bbb R$, and $\langle x,y\rangle$ and $\langle s,t\rangle$ both lie on the line $y=2x-\alpha$.
Note that all of these lines have the same slope, $2$, so they must be parallel: each point of the plane lies on exactly one of them.
With this geometric model in mind, it’s easy to check that $R$ is an equivalence relation whose equivalence classes are precisely the lines $y=2x-\alpha$ for all possible real values of $\alpha$.