As far as I know, this constant does not have a closed-form expression in terms of elementary functions. That said, we can express it in closed form in terms of the Modified Bessel Function of the First Kind, $I_\alpha(x)$, which is defined as
$$I_\alpha(x) := i^{-\alpha} J_\alpha(i x) \sum_{m = 0}^\infty \frac{1}{m! \Gamma(m + \alpha + 1)} \left(\frac{x}2\right)^{2 m + \alpha} .$$
Here, $J_\alpha(x)$ is the (unmodified) Bessel Function of the First Kind, which satisfies a similar differential equation.
Fixing $\alpha = 0$ gives
$$I_0(x) = J_0(i x) = \sum_{n = 0}^\infty \frac{1}{m!^2} \left(\frac{x}2\right)^{2 m},$$
and setting $x = 2$ gives that our sum is
$$\sum_{m = 0}^\infty \frac{1}{m!^2} = I_0(2) = J_0(-2 i) = 2.279585302\ldots .$$
More generally, substituting $u = \frac{x^2}{4}$ in our expression for $I_0(x)$ gives that the series in @KamalSaleh's comment has value
$$\sum_{m = 0}^\infty \frac{u^i}{i!^2} = I_0(2 \sqrt u)$$ for suitable $u$.
Alternatively, it follows from the definition of hypergeometric function that we can write
$$\sum_{m = 0}^\infty \frac{1}{i!^2} = {}_0 F_1(1; 1) ,$$
and more generally that
$$\sum_{m = 0}^\infty \frac{u^m}{m!^2} = {}_0 F_1(1; u) .$$
(Even) more generally, for positive integers $k$,
$$\sum_{m = 0}^\infty \frac{u^m}{m!^k} = {}_0 F_{k - 1}(\underbrace{1, \ldots, 1}_{k - 1}; u) .$$
Where the summands are defined, where $|u| < 1$ and as $k \searrow 0$, linearizing the series in $u$ gives the expansion
$$\sum_{m = 0}^\infty \frac{u^m}{m!^k} \sim \frac{1}{1 - u} - \sum_{m = 0}^\infty u^m \log (m!) \cdot k + R(k) ,$$ where $R(k) \in O(k^2)$.