Your space is (subtlely) already in $\pi$-Base, under the name S133: Post office metric on the plane.
I'll prove something a bit more general. Let $X$ be a metric space containing a point $0$, and let the sets $A_0=X\setminus B_1(0)$ and $A_{n+1}=B_{1/2^n}(0)\setminus B_{1/2^{n+1}}(0)$. Note $X\setminus\{0\}=\bigcup\{A_n:n<\omega\}$ and suppose $|A_n|=|\mathbb R|$ for all $n<\omega$. Give $X$ the post-office metric $$
d(x,y)=
\begin{cases}
0 &\text{if }x=y\\
d(x,0)+d(0,y)&\text{otherwise}
\end{cases}
$$
I claim that $X$ is homeomorphic to your space $\mathbb R$. Let $\theta:X\to\mathbb R$ be defined as follows. First, choose $\theta\upharpoonright A_0$ to be an arbitrary bijection from $A_0$ to $\mathbb R\setminus(-1,1)$. Then, choose $\theta\upharpoonright A_{n+1}$to be an arbitrary bijection from $A_{n+1}$ to $(-1/2^{n},1/2^n)\setminus(-1/2^{n+1},1/2^{n+1})$. Finally, let $\theta(0)=0$.
We have a bijection, so we now show it is a continuous open map.
To see that it is open, let $x\in X\setminus\{0\}$. Then $\{x\}$ is open, and $\theta[\{x\}]\subseteq\mathbb R\setminus\{0\}$ is open. For $0\in X$, choose the basic open set $B_{1/2^n}(0)$. Then $\theta[B_{1/2^n}(0)]=(-1/2^n,1/2^n)$ is open.
To see that it is continuous, let $y\in \mathbb R\setminus\{0\}$. Then $\{y\}$ is open, and $\theta^\leftarrow[\{y\}]\subseteq X\setminus\{0\}$ is open. For $0\in\mathbb R$, choose the basic open set $(-1/2^n,1/2^n)$. Then $\theta^\leftarrow[(-1/2^n,1/2^n)]=B_{1/2^n}(0)$ is open.
I'd very much appreciate it if you'd like to contribute this new perspective on S133 to the $\pi$-Base. I'll create an issue and link it here.
Cardinality $=\mathfrak c$+~Discrete+Has an isolated point+$T_2$– Steven Clontz Dec 26 '23 at 22:07