By contrapositive, the OP's statements are equivalent to
$(1)$ $KL \gt \frac{1}{2}AB \implies \angle KCL \gt \frac{1}{2} \angle ACB$,
$(2)$ $KL \gt \frac{1}{3}AB \implies \angle KCL \gt \frac{1}{3} \angle ACB$.
It turns out that statement $(1)$ $(n=2)$ is true and statement $(2)$ $(n=3)$ is false.
Let us first show that the case $n=3$ is false by a counter example:

In the figure, $\Delta ABC$ is an equilateral triangle with $AB=BC=CA=3$.
Let $K$ coincide with $A$ and $KL=1.01$ such that $KL \gt \frac{1}{3}AB$.
By cosine rule,
\begin{align}
CL^2 &= 3^2+1.01^2-2(3)(1.01)\cos 60^{\text o} \\
CL &=2.643880 \\
\end{align}
By sine rule,
\begin{align}
\frac{\sin \angle KCL}{1.01} &=\frac{\sin 60^{\text o}}{CL} \\
\sin \angle KCL &=\frac{1.01 \times \sin 60^{\text o}}{2.643880} \\
\angle KCL &=19.31941^{\text o}
\end{align}
$\because \frac{1}{3}\angle ACB=20^{\text o}$
$\therefore \angle KCL \lt \frac{1}{3}\angle ACB $
$\therefore KL \gt \frac{1}{3}AB$ does not imply $\angle KCL \gt \frac{1}{3}\angle ACB$.
The claim for $n=3$ is therefore false.
Next we are going to prove that the case for $n=2$ is true.
i.e. $KL \gt \frac{1}{2}AB \implies \angle KCL \gt \frac{1}{2} \angle ACB$.
We first state an obvious lemma:

In the figure, $\Delta XYZ$ is a triangle in which $XY, XZ$ have fixed lengths. If $\theta$ varies between $0^{\text o}$ and $180^{\text o}$, then the greater the value of $\theta$, the greater the length of $YZ$.
The converse is also true.
Now for the proof:

In the figure, $D$ is constucted so that $BD=AK$, $CD=CK$.
Note that $$\Delta CAK \cong \Delta CBD$$
Hence $$\angle ACK=\angle BCD$$
Note that $KL \gt \frac{1}{2}AB \implies KL \gt AK+LB$
$\therefore KL \gt LB + BD$
This in turns implies that $KL \gt LD$.
Since $CL=CL$ and $CK=CD$, $KL \gt LD$,
by our lemma, $\angle KCL \gt \angle LCD$.
Noting that $\angle KCL + \angle LCD = \angle ACB$.
This implies that $\angle KCL \gt \frac{1}{2} \angle ACB$.
This complete the proof.