When we expand $$(w+x+y+z)^{10}$$ we obtain a sum of degree $10$ monomials.
We get a $+1$ contribution to the coefficient of $w^3x^5z^2$ from the coefficients highlighted below:
$$(\color{blue}{\bf w}+x+y+z)(\color{blue}{\bf w}+x+y+z)(\color{blue}{\bf w}+x+y+z)(w+\color{red}{\bf x}+y+z)(w+\color{red}{\bf x}+y+z) \times\\
(w+\color{red}{\bf x}+y+z)(w+\color{red}{\bf x}+y+z)(w+\color{red}{\bf x}+y+z)(w+x+y+\color{green}{\bf z})(w+x+y+\color{green}{\bf z})$$
$$(w+\color{red}{\bf x}+y+z)(w+x+y+\color{green}{\bf z})(\color{blue}{\bf w}+x+y+z)(w+\color{red}{\bf x}+y+z)(w+\color{red}{\bf x}+y+z) \times\\
(\color{blue}{\bf w}+x+y+z)(\color{blue}{\bf w}+x+y+z)(w+\color{red}{\bf x}+y+z)(w+x+y+\color{green}{\bf z})(w+\color{red}{\bf x}+y+z)$$
and so on.
If we write down the highlighted terms as a list, we get $$wwwxxxxxzz$$ and $$xzwxxwwxzx$$ for the two cases above.
So, the contributions to the coefficient of $w^3x^5z^2$ correspond to orderings (or multiset permutations) of the multiset $$\{w,w,w,x,x,x,x,x,z,z\}.$$ There are $$\binom{10}{3,5,2}$$ such orderings; this is counted by the multinomial coefficient.