As said, factor $$2x^2+5y^2-11xy=(x-5y)(2x-y)$$
We have the following cases:
$-25=-1\cdot 25$. Solve the systems:
$$\begin{cases}x-5y=-1\\2x-y=25\end{cases}\:\Longrightarrow\:\boxed{(x,y)=(14,3)}$$
and $$\begin{cases}x-5y=25\\2x-y=-1\end{cases}\:\Longrightarrow\:(x,y)=\left(-\frac{10}{3},-\frac{17}{3}\right)$$
We can't accept this last solution, since $x$ and $y$ are not natural numbers.
$-25=-5\cdot 5$. Solve:
$$\begin{cases}x-5y=-5\\2x-y=5\end{cases}\:\Longrightarrow\:(x,y)=\left(\frac{10}{3},\frac{5}{3}\right)$$
and
$$\begin{cases}x-5y=5\\2x-y=-5\end{cases}\:\Longrightarrow\:(x,y)=\left(-\frac{10}{3},-\frac{5}{3}\right)$$
None of the solutions can be accepted.
So, the only solution is: $$\boxed{(x,y)=(14,3)}$$
Further details: At first glance it seems we have to analyze also the case $-25=-25\cdot 1$, so that we have to solve the systems:
$$\begin{cases}x-5y=-25\\2x-y=1\end{cases}$$ and $$\begin{cases}x-5y=1\\2x-y=-25\end{cases}$$ Observing that they only have opposite signs compared to the first case we analyzed, the solutions are, respectively, $\left(\frac{10}{3},\frac{17}{3}\right)$ and $(-14,-3)$. Neither of them can be accepted, since the solutions are not natural numbers.
Edit 2: How did I obtain the factorization $2x^2+5y^2-11xy=(x-5y)(2x-y)$? I just looked for a decomposition of the form $$2x^2+5y^2-11xy=(x+ay)(2x+by)$$ and solved for some $a$ and $b$...