Unfortunately this answer is not quite finished, but I have to run, so posting it here to save it and/or have others finish it.
Let $a\in\Bbb{R}_{>0}$ be a positive real number, and let $t\in\Bbb{R}$ be a real number such that
$$a^{2t} + a^{\frac2t} = a^{1+t} + a^{1+ \frac1t}.\tag{0}$$
First note that $t=1$ is a solution for any $a\in\Bbb{R}_{>0}$, so we will only consider $t\neq1$ from here on. Similarly, for $a=1$ any $t\in\Bbb{R}$ is a solution, so we will only consider $a\neq1$ from here on. We will also not consider $t=0$, as the original equation is not defined at this point.
Let $b:=a^{\tfrac1t}$ so that $a=b^t$ and hence
$$b^{2t^2}+b^2=b^{t^2+t}+b^{t+1}.$$
Rearranging, dividing by $b^2$ and factoring the exponents, we find that
$$b^{2(t+1)(t-1)}-b^{(t+2)(t-1)}-b^{t-1}+1=0,$$
and hence for $c:=b^{t-1}$ that
$$(c^t)^2-c^t=\frac{c-1}{c^2}.\tag{1}$$
Note that $c=a^{\frac{t-1}{t}}$ is again a positive real number, and that conversely, if $c\in\Bbb{R}_{>0}$ is a positive real number and $t\in\Bbb{R}$ a real number satisfying $(1)$, then $a:=c^{\frac{t}{t-1}}$ and $t$ satisfy the original equation $(0)$. So it suffices to find all solutions to $(1)$, where we only consider solutions with $t\neq1$ and $a\neq1$, and hence $c\neq1$.
Let $C\in\Bbb{R}_{>0}$ be a positive real constant different from $1$, and consider the real-valued function
$$f:\ \Bbb{R}\ \longrightarrow\ \Bbb{R}:\ x\ \longmapsto\ (C^x)^2-C^x.$$
It is easy to see that $\lim_{x\to\infty}f(x)=0$ if $C<1$
With some basic calculus we find that
$$f'(x)=C^x(2C^x-1)\ln C,$$
from which it follows that $f'(x)=0$ if and only if $x=-\frac{\ln 2}{\ln C}$, and we readily see that $-\tfrac14$ is the unique minimum of $f$ at $x_0:=-\frac{\ln 2}{\ln C}$. Clearly $f(0)=0$ regardless of the value of $C$, and so we see that:
- If $C>1$ then $\lim_{x\to-\infty}f(x)=0$. It follows that $f(x)<0$ for all $x<0$. Because $\frac{C-1}{C^2}>0$ we see that there is no solution to $(1)$ with $c>1$ and $t\leq0$.
- If $C<1$ then $\lim_{x\to-\infty}=\infty$. It follows that $f(x)>0$ for all $x<0$. Because $\frac{C-1}{C^2}<0$ we see that there is no solution to $(1)$ where $c<1$ and $t\leq0$.
In conclusion, if $(c,t)$ is a solution to $(1)$ with $c\neq1$ then $t>0$. Correspondingly, if $(a,t)$ is a solution to $(0)$ with $a\neq1$ then $t>0$.
Now viewing $(1)$ as a quadratic in $c^t$ we find that
$$c^t=\frac{1\pm\sqrt{1+4\frac{c-1}{c^2}}}{2}.$$
In particular we see that there is no solution if $1+4\frac{c-1}{c^2}<0$, or equivalently $c<2\sqrt{2}-2$.
If $c>1$ then $\sqrt{1+4\frac{c-1}{c^2}}>1$ and so we must have the $+$-sign, because of course $c^t>0$. Similarly, if $c<1$ then $c^t<1$ because we saw that $t>0$, and so we must have the $-$-sign. With this in mind we find that
$$t(c)=\frac{\ln\tfrac12\left(1\pm\sqrt{1+4\frac{c-1}{c^2}}\right)}{\ln c},$$
and correspondingly $a=c^{\frac{t(c)}{t(c)-1}}$.
For $c>1$ it is not difficult to check that $t(c)<1$ and hence that $a=c^{\frac{t}{t-1}}<1$, and that $t(c)$ is strictly decreasing. For $c<1$ we already noted that $t(c)$ is not defined whenever $c<2\sqrt{2}-2$. For $c\geq2\sqrt{2}-2$ we see that $t(c)$ is strictly increasing with $t(2\sqrt{2}-2)\approx3.6825\ldots$. Again we see that $a=c^{\frac{t(c)}{t(c)-1}}<1$.
In particular, we see that there are no solutions with $a>1$.
Some unsorted ideas.
Now suppose $C<1$. Then $f(0)=0$ and $\lim_{x\to\infty}f(x)=0$, and the unique extremum of $f$ is $f(x_0)=-\tfrac14$ at $x_0:=-\frac{\ln 2}{\ln C}$. This already shows that we cannot have
$$(C^x)^2-C^x=\frac{C-1}{C^2},$$
if $\frac{C-1}{C^2}<-\frac14$, or equivalently, if $C<2\sqrt{2}-2\approx0.8284\ldots$. But if $C\geq2\sqrt{2}-2$ then
Now suppose $C>1$. Then $f(0)=0$ and $\lim_{x\to\infty}f(x)=\infty$, and $f'(x)>0$ for all $x>0$, and so there is precisely one real number $t\in\Bbb{R}$ such that
$$(C^t)^2-C^t=\frac{C-1}{C^2}.\tag{2}$$
Denote this value by $t(C)$. Then we have seen before that $t(C)>0$. Viewing the right hand side of $(2)$ as a function of $C$, it is easily verified to have a maximum of $\tfrac14$ at $C=2$. This means
$$(C^{t(C)})^2-C^{t(C)}=\frac{C-1}{C^2}\leq\frac14,$$
which already tells us that
$$t(C)\leq\frac{\ln\left(\tfrac{1+\sqrt{2}}{2}\right)}{\ln C}.$$
In particular, for $C>\tfrac{1+\sqrt{2}}{2}$ we see that $t(C)<1$ and hence that $a:=C^{\frac{t(C)}{t(C)-1}}<1$.
For $C\leq\tfrac{1+\sqrt{2}}{2}$ we find that
$$\frac{C-1}{C^2}\leq-14+10\sqrt{2}\approx0.14214\ldots,$$
which as before tells us that
$$t(C)\leq\frac{\ln\frac12\sqrt{40\sqrt{2}-55}}{\ln C},$$
and as before, this in turn for $C>\frac12\sqrt{40\sqrt{2}-55}$ implies that $a:=C^{\frac{t(C)}{t(C)-1}}<1$.
[Iterating this process will show that for every $C>1$ we get $t(C)<1$ and hence $a:=C^{\tfrac{t(C)}{t(C)-1}}<1$. I have not made this rigorous yet, and there must be a nicer way to go about showing this.]