$P_n[0,1]$ is an $n+1$-dimensional subspace of $C[0,1]$. In any topological vector space, a finite-dimensional subspace is closed. So, yes, $P_n[0,1]$ is closed in $C[0,1]$ with respect to the uniform norm (sup norm). In fact, the same is also true for any other norm that makes $C[0,1]$ a topological vector space.
The fact that finite-dimensional subspaces are closed is fairly well known, I think. There's a proof in these notes. Please see theorem 3G on page 8. The proof seems very long and roundabout, to me. I'll look for something shorter/simpler.
A nicer proof (in my opinion) can be found here, paraphrased from Bourbaki, which is where I must have learned all this, I suppose, many decades ago.
Just discovered that the question is a duplicate of this one, which has good answers.