I'm assuming you have a matrix equation of the form $Ax = b$. A row of the augmented matrix corresponds to a linear equation with $x_1, x_2, \ldots, x_n$ as the unknowns.
Let the two rows you are adding be $[p_1~p_2~\cdots~p_n~c]$ and $[q_1~q_2~\cdots~q_n~d]$, where the $p_i$ and $q_i$ are from $A$, and $c$ and $d$ from $b$. These correspond to the equations:
$$p_1 x_1 + p_2 x_2 + \cdots + p_n x_n = c \qquad (1)$$
$$q_1 x_1 + q_2 x_2 + \cdots + q_n x_n = d \qquad (2)$$
If you add $k$ times the first row to the second, you get a new second row $[kp_1 + q_1~kp_2 + q_2~\cdots~kp_n + q_n~kc + d]$, which corresponds to this equation:
$$ (kp_1 + q_1) x_1 + (kp_2 + q_2) x_2 + \cdots + (kp_n + q_n) x_n = kc + d \qquad (2^\prime)$$
The hardest part about this is justifying what exactly you need to check. We must show that $x$ satisfies $(1)$ and $(2)$ if and only if it satisfies $(1)$ and $(2^\prime)$. Checking that these are true just relies on a bunch of distributing and whatever the name for this theorem is: $u = v \textrm{ and } x = y \implies u + x = v + y$.
Forward direction:
Assume $(1)$ and $(2)$ are true. Then $kp_1 x_1 + kp_2 x_2 + \cdots + kp_n x_n = kc$, because we can multiply both sides of an equation by a constant. Then, we can add $(2)$ to this, getting: $(kp_1 + q_1) x_1 + (kp_2 + q_2) x_2 + \cdots + (kp_n + q_n) x_n = kc + d$, which is exactly what we wanted to show, i.e. equation $(2^\prime)$.
Reverse direction is similar, see if you can work out the details.