Suppose that you want to pick a team of $n+1$ people from a group of $2n$ candidates, and you want to designate one member of the team as the captain. No two candidates are the same height, and the tallest member of the team is not allowed to be the captain. You can choose the team in $\binom{2n}{n+1}$ ways, and you then have $n$ choices for the captain, so you can complete the selection in $n\binom{2n}{n+1}$ ways.
Let the candidates be $c_1,c_2,\ldots,c_{2n}$, arranged in order of increasing height. Clearly a team of $n+1$ people will include at least one person from the set $U=\{c_{n+1},c_{n+2},\ldots,c_{2n}\}$; in particular, the tallest member of the team will be from $U$. For $k=1,\ldots,n$, how many ways are there to select the team so that $c_{n+k}$ is its tallest member?
We can do it by selecting $n-1$ team members from $\{c_1,c_2,\ldots,c_{n-1+k}\}$, which can be done in $$\binom{n-1+k}{n-1}=\binom{n-1+k}k$$ ways, and then selecting one of the remaining $k$ members of the set $\{c_1,c_2,\ldots,c_{n-1+k}\}$ to be the captain. This last step can be done in $k$ ways, so there are $k\binom{n-1+k}k$ ways to select a team whose tallest member is $c_{n+k}$. Since $k$ can be any element of $\{1,2,\ldots,n\}$, it follows that
$$\sum_{k=1}^nk\binom{n-1+k}k=n\binom{2n}{n+1}\;.$$