I think it is. Since we are dealing with a subset of a metrical space, the limit points are real numbers that are the limit of a sequence of elements in that set, unequal to the limit itself.
Such a sequence $(a_i)$ is of the form $({1\over n_i} + {1\over m_i})$, so we have two sequences of natural numbers $(n_i)$ and $(m_i)$ (not uniquely determined by $(a_i)$ but that doesn't matter).
If one of these can get arbitrarily large, say a subsequence of $(n_i)$ goes to infinity, then a subsequence of $(a_i)$ goes to the limit of the corresponding subsequence of the sequence $({1\over m_i})$, which exists, because otherwise the original sequence wouldn't have a limit either. This gives the limit points of the form ${1\over m}$.
If neither grows arbitrarily large, there is only a finite number of possibilities for $a_i = {1\over n_i} + {1\over m_i}$, so the limit must be an element of the sequence, and by definition is not a limit point.