Let Spec${A}$ be an affine scheme, can every open affine subscheme be written as Spec$A_f$ for some $f$ in $A$?
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No. Counterexamples are discussed at MO/7153. The example by Hailong Dao is really elementary: $A=k[X,Y,U,V]/(XY+UX^2+VY^2)$, then $D(X) \cup D(Y)$ is affine, but not basic-open.
Martin Brandenburg
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1Why is $D(X) \cup D(Y)$ not basic-open? This was not answered over at MO. – red_trumpet Sep 17 '18 at 12:49