I think it might be helpful to rewrite it slightly:
$$
\frac{mn}{1+m+n}=\frac{n}{\frac{1}{m}+1+\frac{n}{m}}
$$
For fixed $n$, as $m$ increases this increases as well. Same goes for the reversed case. Hence, $\sup A$ should be $\infty$. For as small a value as possible, $m$ should then be as small as possible since this means that the denominator is as large as possible. So $m=1$. What's left is
$$
\frac{n}{2+n}=\frac{1}{\frac{2}{n}+1}
$$
which obviously is as small as possible when the denominator is as large as possible -- i.e. when $n=1$. So $\inf=1/3$, which is achieved when $n=m=1$.